The TV will have a rating plate on the back somewhere that carries the serial number and lots of other information inc. the operating voltage.
BUT there is an easier way - what sort of power cord does the TV have?
Is it one that ends with a standard 3 pin plug or is it one that plugs into the back of the set and has a cigar lighter plug on the other end.
If 1 it is a mains (240v) TV if 2 then it is a 12v (or just possibly 24v - but very unlikely) TV that will run straight off the leisure battery.
Beware of running anything like an inverter straight off the starter battery as they use a lot of power and can flatten a battery very quickly - you do not want to keep flattening a starter battery.